The notion of a complete Boolean algebra, although completely legitimate in constructive mathematics, fails to capture some natural structures such as the lattice of subsets of a given set. Sambin's notion of an overlap algebra, although classically equivalent to that of a complete Boolean algebra, has powersets and other natural structures as instances. In this paper we study the category of overlap algebras as an extension of the category of sets and relations, and we establish some basic facts about mono-epi-isomorphisms and (co)limits; here a morphism is a symmetrizable function (with classical logic this is just a function which preserves joins). Then we specialize to the case of morphisms which preserve also finite meets: classically, this is the usual category of complete Boolean algebras. Finally, we connect overlap algebras with locales, and their morphisms with open maps between locales, thus obtaining constructive versions of some results about Boolean locales.