The problem of model checking procedural programs has fostered much research towards the definition of temporal logics for reasoning on context-free structures. The most notable of such results are temporal logics on Nested Words, such as CaRet and NWTL. Recently, the logic OPTL was introduced, based on the class of Operator Precedence Languages (OPLs), more powerful than Nested Words. We define the new OPL-based logic POTL and prove its FO-completeness. POTL improves on NWTL by enabling the formulation of requirements involving pre/post-conditions, stack inspection, and others in the presence of exception-like constructs. It improves on OPTL too, which instead we show not to be FO-complete; it also allows to express more easily stack inspection and function-local properties. In a companion paper we report a model checking procedure for POTL and experimental results based on a prototype tool developed therefor. For completeness a short summary of this complementary result is provided in this paper too.